Sam-Shajing Sun, Ph.D.

Professor of Chemistry and Materials Science

Head, Organic and Polymeric Materials Research Labs

Director, Center for Organic Photonic Materials Research

Director, Center for Research and Education in Advanced Materials

Center for Materials Research &  Chemistry Department, Norfolk State University

700 Park Avenue
Norfolk, VA 23504

Phone:  757-823-2993
Fax: 757-823-9054 
Email: ssun@nsu.edu

Office: MVM 511
Labs: MVM 302, 304, 306

 

Brief Biography

 

Dr. Sun obtained his B.S. degree in physical chemistry from Peking University (Beijing, China), his M.S. degree in inorganic/analytical/Nuclear chemistry from California State University (Northridge, California), and his Ph.D. degree in organic/polymer/materials chemistry from the University of Southern California (Los Angeles, California, 1996).  After a postdoctoral fellowship appointment at the Loker Hydrocarbon Research Institute (Director: George Olah, Co-director: Larry Dalton), Dr. Sun joined the Chemistry Department and the Center for Materials Research (CMR) at Norfolk State University as a tenure-track faculty member in spring of 1998.  He was promoted to associate professor (with tenure) in the spring of 2002, and was promoted to full professor in spring 2006.  Dr. Sun is a member and a technical referee in a number of international scientific societies, including the International Society for Optical Engineering (SPIE), Materials Research Society (MRS), American Chemical Society (ACS), Optical Society of America (OSA), International Solar Energy Society (ISES), American Solar Energy Society (ASES), American Institute of Aerospace and Aeronautics (AIAA), American Association for the Advancement of Science (AAAS), etc.  Dr. Sun is also an associate editor in charge of organic/polymeric solar cell paper publications for the Solar Energy journal, the official journal of the ISES.  Dr. Sun also serves on the editorial board of a new journal Research Letters In Materials Science.  

Research Expertise and Interests

Professor Sun's research expertise and interests include the design, synthesis, processing, characterization, and modeling of novel supramolecular nano structured polymeric solid state materials and thin films devices for electronic, photonic, optoelectronic, and solar energy conversion applications.  His research group is currently investigating and developing novel polymeric materials with unique supra-molecular nano structures and functional groups, for instance, unique donor-bridge-acceptor type block copolymer and its bicontinuous ordered nano structures (BONS) for photo detector and solar cell device applications.   

Academic and Professional Activities

Since joining Norfolk State University (NSU) in 1998, Prof. Sun has established from scratch a state-of-the-art organic and polymeric materials research program and labs at NSU. In addition to classroom teaching of undergraduate and graduate courses including "General Chemistry", "Organic Chemistry", "Advanced Organic Chemistry", “Chemistry Seminars”, "Polymers", "Special Topics", "Advanced Research", "MS Thesis" at NSU chemistry department and materials science graduate program, Prof. Sun is also supervising an organic and polymeric advanced materials research group consisting of 2-3 research faculty, 5-7 graduate students, and a number of undergraduate students.  Recently, Professor Sun has founded and is directing a "Center for Organic Photonic Materials Research" or "COPMR" which also includes research groups of Prof. Carl E. Bonner (Optical Laser Spectroscopy), Prof. Rakhim Rakhimov (Electron Spin Resonance Spectroscopy) and other collaborators.  Current research projects mainly include development of novel supra-molecular and nano structured conjugated block copolymer systems for potential photo detector and solar energy conversion (solar cell) applications.  In 2005, Prof. Sun edited a CRC Press’s new book titled "Organic Photovoltaics: Mechanisms, Materials and Devices" (ISBN 0-82475-963-X. See http://www.crcpress.com/shopping_cart/products/product_detail.asp?sku=DK963X&parent_id=&pc= ).  This book has contributions from over 60 prominent scientists/experts in the field around the globe.  More recently, Prof. Sun also edited a new CRC Press textbook titled “Introduction to Organic Electronic and Optoelectronic Materials and Devices” to be published during 2008 (ISBN: 9780849392849).  This book has thirty (30) chapters covering comprehensively all aspects of organic and polymeric electronic and optoelectronic materials and devices, and it is in fact the first textbook of its kind in the field.  The optoelectronic polymer research and educational projects Prof. Sun is leading have been supported by the university, the Dozoretz Foundation, and particularly by a number of government agencies including NASA, Department of Defense (MDA, AFOSR, ARO), National Science Foundation, Department of Energy, and Department of Education.  Prof. Sun is now also leading a "Center for Research and Education in Advanced Materials" or "CREAM" (supported by NASA), where Professor Sun's photovoltaic materials research and educational project is a critical component.  Professor Sun has been very active in publishing and presenting in the area of organic and polymeric functional electro-active materials and thin film devices.  Prof. Sun is also invited for many volunteer professional duties, these include refereeing technical publications for professional societies and major publishers including ISES, ACS, APS, AIP, MRS, SPIE; OSA, Elsevier, Wiley, Springer, CRC, reviewing proposals for agencies such as NSF, DOE, NASA, AFOSR, CRDF, Bank of America, ACS-PRF, Canada Council for the Arts, Netherlands Organization for Scientific Research (NWO), etc.  At NSU, Professor Sun has been awarded a number of honors or titles by his colleagues and leadership, these include "Outstanding Mentor", "Outstanding Scholar", "Researcher of the Year", and the ‘Eminent Scholar’ of NSU. 

Some representative publications relevant to organic/polymeric electro-active materials. 

 

-Sun, S. and Dalton, L. eds, Introduction to Organic Electronic and Optoelectronic Materials and Devices, CRC Press: Boca Raton, Florida, 2008 (ISBN-10: 0849392845; ISBN-13: 978-0849392849). 

 

-Sun, S., “Polymer Photovoltaic Optimizations From Exciton Level”, J. Mater. Sci., 2007, 18, 1143-1146. 

 

-Sun, S., Zhang, C. Choi, S.; Ledbetter, A.; Bonner, C.; Drees, M.; Sariciftci, S., “Photovoltaic enhancement of organic solar cells by a bridged donor-acceptor block-copolymer approach”, Appl. Phys. Lett., 2007, 90, 043117.

 

-Sun, S. “Recent Progress of Organic Photovoltaics”, an invited review article in Advances in Solar Energy, edited by Y. Goswami, International Solar Energy Society, Freiburg, Germany, 2007, 17, Chapter 3, 74-98.

 

-Zhang, C. and Sun, S., “Efficient Synthesis of an Aldehyde-Capped Polythiophene Containing Fluorinated Electron-Withdrawing Groups”, J. Poly. Sci. (A) Polym. Chem., 2007, 45, 41-47.

 

-Sun, S. “Organic and Polymeric Solar Cells”, an invited review article in Handbook of Organic Electronics and Photonics, edited by S. H. Nalwa, American Scientific Publishers, Los Angeles, California, 2006, vol. 2, chapter 23. 

 

-Zhang, C.; Choi, S.; Haliburton, J.; Li, R.; Cleveland, T.; Sun, S.; Ledbetter, A.; Bonner, C.; “Design, Synthesis, and Characterization of a -Donor-Bridge-Acceptor-Bridge- Type Block Copolymer via Alkoxy and Sulfone Derivatized Polyphenylenevinylenes, Macromolecules, 2006, 39, 4317-4326.

 

-Sun, S. and Sariciftci, S., eds., Organic Photovoltaics: Mechanisms, Materials and Devices, CRC Press, Boca Raton, Florida, 2005 (ISBN-10: 0-8247-5963-X; ISBN-13: 978-0824759636). 

 

-Sun, S. et al., “Chapter 8: Optimizations of Organic Solar Cells in Both Space and Energy/Time Domains”, in Organic Photovoltaics: Mechanisms, Materials and Devices, edited by Sun and Sariciftci, CRC Press, Boca Raton, Florida, 2005, pp183-214. 

 

-Sun, S., et al., “Synthesis and Characterization of a New Acceptor (N-type) Fluorinated and Terminal Functionalized Polythiophene”, J. Poly. Sci. (A) Poly. Chem., 43, 4280-4287 (2005).

-Sun, S.; et al. “Organic Solar Cell Optimizations”, J. Mater. Sci., 40, 1429-1443 (2005).

-Sun, S., “Optimal Energy Offsets for Organic Solar Cells Containing a Donor/Acceptor Pair”, Sol. Energy Mater. Sol. Cel., 85, 261-267 (2005).

-Sun, S.; et al., “Morphological Effects to Carrier Mobility in a RO-PPV/SF-PPV Donor/Acceptor Binary Thin Film Opto-electronic Device”, Mater. Sci. & Eng. B, 116, 279-282 (2005).

-Sun, S., “Optimal energy levels for organic donor/acceptor binary photovoltaic materials and solar cells”, Mater. Sci. & Eng., B, 116, 251-256 (2005).

-Sun, S.; “Polymer Morphology and Energy Levels Versus Photoelectric Power Conversion Efficiencies: A Preliminary Account”, in Organic Photovoltaics V, SPIE, 5520, 126-135 (2004).

-Sun, S.; et al., “Fumaryl Chloride and Maleic Anhydride Derived Crosslinked Functional Polymers for NLO Waveguide Applications”, J. Appl. Poly. Sci., 92, 317-322 (2004). 

 

-Sun, S., “Design of a Block Copolymer Solar Cell”, Sol. Energy Mater. Sol. Cel., 79, 257 (2003).

 

-Sun, S. et al., “Conjugated Block Copolymers for Opto-Electronic Functions”, Syn. Met., 137, 883-884 (2003).

 

 -Sun, S., et al., “Synthesis and Characterization of a Novel -DBAB- Type Block Copolymer System for Light Harvesting Applications”, SPIE, 4801, 114-124 (2003).


-Sun, S., et al., “Chapter 2: Fumaryl Chloride and Maleic Anhydride Derived Crosslinked Functional Polymers and Nano Structures”, in Functional Condensation Polymers, eds., C. Carraher and G. Swift, Kluwer Academic Press, New York, 2002, pp 17-30. 


-Sun, S., et al., “Electrically Conductive Semi-IPNs Based on Polyaniline and Crosslinked Polyvinylacetate”, J. Appl. Poly. Sci., 85(11), 2287-2293 (2002).


-Sun, S., et al., “Synthesis and Characterization of 1,3-bis(dicyanomethylidene)indane (BDMI)-based nonlinear optical polymers”, Polymer, 39(20), 4977 (1998). 


-Sun, S., et al., “Translating Microscopic Optical Nonlinearity into Macroscopic Optical Nonlinearity: the role of chromophore-chromophore electrostatic interactions”, J. Opt. Soc. Am. (B)., 15(1), 329 (1998). 


-Sun, S., et al.,”1,3-Bis(dicyanomethylidene) indane-Based Second-Order NLO Materials”, Chem. Matter., 8, 2539 (1996). 

-Sun, S.; et al., “Processible and Thermally Stable Heterocyclic Polymers for Second-Order Nonlinear Optical Studies”, Chem. Matter., 8, 2681 (1996). 

Photo 1: Prof. Sun’s Organic/Polymeric Materials Research Group

Photo 2: Professor Sun with his new book "Organic Photovoltaics: Mechanisms, Materials and Devices" (CRC Press, 2005).

Photo 3: Professor Sun was supervising a student researcher.

Photo 4: Professor Sun was lecturing to graduate students.


 

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